Highly soluble small-molecule organic semiconductor with trihexylsilyloxy side chain for high-performance organic field-effect transistors with mobility of up to 3.10 cm2 V−1 s−1
- 저자
- Bogyu Lim, Huabin Sun, Yong-Young Noh*
- 저널명
- Dyes and Pigments, 142, 17-23 (2017)
- 년도
- 2017
- Link
- https://doi.org/10.1016/j.dyepig.2017.03.025 179회 연결
[Abstract]
A donor–acceptor type small molecule organic semiconductor with a trihexylsilyloxy bulky side chain, coded LGC-D127, was synthesized, and its electronic, electrochemical, and electrical properties were investigated for use as the active layer of solution-processable organic field-effect transistors. LGC-D127 consisted of a phenylene–dithiophene moiety with a bulky trihexylsilyloxy side chain as the electron-donating core, diketopyrrolopyrrole as the electron-accepting linker, and octylrhodanine as the electron-accepting end group. In spite of bulky trihexylsilyloxy side chains, LGC-D127 film was highly crystalline. The charge-carrier transport properties of the LGC-D127 was investigated through the fabrication and characterization of field-effect transistor via solution process. LGC-D127 showed significantly high field-effect hole mobility of 3.16 cm2 V−1 s−1 after thermal annealing due to the large crystalline nanostructure and the small grain boundaries. In particular, LGC-D127 had good solubility in the environmentally friendly solvent such as 2-methyltetrahydrofuran due to the bulky trihexylsilyloxy side chain, and its high hole mobility (max. 3.06 cm2 V−1 s−1) was sustained from the LGC-D127 solution in 2-methyltetrahydrofuran.